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Cu(II)-Aza(bisoxazoline)-Catalyzed Asymmetric Benzoylations

Gissibl, Anja and Finn, M. G. and Reiser, Oliver (2005) Cu(II)-Aza(bisoxazoline)-Catalyzed Asymmetric Benzoylations. Organic Letters 7 (12), pp. 2325-2328.

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Other URL: http://dx.doi.org/10.1021/ol0505252


Abstract

Racemic 1,2-diols and α-hydroxy carbonyl compounds can be asymmetrically benzoylated in a kinetic resolution in the presence of various Cu(II)-aza(bisoxazoline) catalysts. A novel bisbenzyl-substituted aza(bisoxazoline) ligand proved to be especially effective when immobilized on MeOPEG5000, giving from 91 to ≥99% ee in 37-49% yield for each of five sequential ...

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Item Type:Article
Date:9 June 2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ol0505252DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:05 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:357
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