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Synthesis of Chiral Amino Acids with Metal Ion Chelating Side Chains from L-Serine using Negishi Cross-Coupling Reaction

Kruppa, Michael and Imperato, Giovanni and König, Burkhard (2006) Synthesis of Chiral Amino Acids with Metal Ion Chelating Side Chains from L-Serine using Negishi Cross-Coupling Reaction. Tetrahedron 62 (7), pp. 1360-1364.

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Other URL: http://dx.doi.org/10.1016/j.tet.2005.11.034


Abstract

The scope of the Negishi cross-coupling reaction of organozinc compounds derived from chiral amino acids was extended to electron rich iodoanilines and iodobenzylamines as coupling reagents. The protocol allows the direct modification of serine into phenylalanine derivatives bearing metal ion chelating ligands in their side chain, such as amino esters 6 and 7. The preparation of metal complex ...

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Item Type:Article
Date:13 February 2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1016/j.tet.2005.11.034DOI
Keywords:Amino acids; Metal chelates; Organozinc compounds; C–C bond formation; Negishi coupling
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Jul 2006
Last Modified:13 Mar 2014 09:38
Item ID:43
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