Rasappan, R. and Laventine, D. and Reiser, O. (2008) Metal-bis(oxazoline) complexes: From coordination chemistry to asymmetric catalysis. Coordination Chemistry Reviews 252 (5-7), pp. 702-714.
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Metal-bis(oxazoline) complexes have proven to be one of the most versatile classes of chiral catalysts being able to promote a large variety of organic transformations. The coordination geometry and electronic properties play an integral role for the asymmetric induction exhibited by these complexes and, aided by X-ray structure analysis and NMR studies, rules have been recognized to understand their function. Based on the most common complex geometries observed, i.e. tri, tetra- (tetrahedral or square-planar), penta- (trigonal-bipyramidal or square-pyramidal), or hexacoordination (octahedral) a mechanistic picture has emerged that allows control of enantioselectivity in reactions in a highly predictable and tunable way, demonstrating the power of combining the knowledge of coordination chemistry and asymmetric catalysis. (c) 2007 Elsevier B.V. All rights reserved.
|Additional information (public):||Rasappan, Ramesh; Laventine, Dominic; Reiser, Oliver|
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||09 Feb 2009 10:03|
|Last Modified:||16 Nov 2009 14:36|