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Detection of \"Cold\" Spectra from a Room-Temperature Ensemble: Magnetic Rotation Spectroscopy with Simple Interpretation in Terms of Molecular Pendular States

Slenczka, Alkwin (1997) Detection of \"Cold\" Spectra from a Room-Temperature Ensemble: Magnetic Rotation Spectroscopy with Simple Interpretation in Terms of Molecular Pendular States. Journal of Physical Chemistry A 101 (41), pp. 7657-7663.

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Abstract

The anisotropic orientation of the figure axis of pendular mols. is directly detected by polarization spectroscopy for ICl in the excited A 3P1 state. A simple geometric model is outlined that simulates all spectral features over a wide range of exptl. parameters, without any fitting procedure. The exptl. technique, closely related to magnetic rotation spectroscopy, strongly favors low rotational ...

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Item Type:Article
Date:1997
Additional information (public):CAN 127:284995; 73-2; Optical, Electron, and Mass Spectroscopy and Other Related Properties 7790-99-0 (Iodine monochloride) Role: PRP (Properties) (detection of cold spectra from room-temp. ensemble by magnetooptical rotation spectroscopy with simple interpretation in terms of mol. pendular states)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Alkwin Slenczka
Identification Number:
ValueType
1997:623680Other
Keywords:Molecular orientation; Optical anisotropy; Polarized light (detection of cold spectra from room-temp. ensemble by magnetooptical rotation spectroscopy with simple interpretation in terms of mol. pendular states in relation to) Energy level Rotational state (detection of cold spectra from room-temp. ensemble by magnetooptical rotation spectroscopy with simple interpretation in terms of pendular); Faraday effect (detection of cold spectra from room-temp. ensemble with simple interpretation in terms of mol. pendular states); iodine chloride pendular state magnetooptical rotation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Alkwin Slenczka
Deposited On:10 Mar 2009 11:51
Last Modified:05 Aug 2009 13:51
Item ID:6071
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