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Palladium-Catalyzed Coupling of Vinylferrocene with Aromatic Halides - A Highly Efficient Route to (Ferrocenylvinyl)arenes

König, Burkhard and Zieg, H. and Bubenitschek, P. and Jones, P. G. (1994) Palladium-Catalyzed Coupling of Vinylferrocene with Aromatic Halides - A Highly Efficient Route to (Ferrocenylvinyl)arenes. Chemische Berichte 127 (9), pp. 1811-1813.

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Abstract

(Ferrocenylvinyl)arenes 3, 5, and 7 are obtained from vinylferrocene (1) and substituted aromatic and heteroaromatic halides by palladium-catalyzed Heck-type reactions. Up to three ferrocene units are introduced in one step by the multi-fold reaction of 1,2-dibromo- (4) or 1,3,5-tribromobenzene (6) with 1. The first crystal structure of a bis(ferrocenylvinyl)benzene chromophore (5) is reported.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1002/cber.19941270935DOI
Keywords:Vinylferrocene , Palladium-catalyzed couplin , (Ferrocenylvinyl)arenes
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner:Universitätsbibliothek Regensburg
Deposited On:05 Mar 2009 11:53
Last Modified:20 Jul 2011 23:25
Item ID:6164
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