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Design of a Neutral Macrocyclic Ionophore, Synthesis and Binding Properties for Nitrate and Bromide Anions

Herges, R. ; Dikmans, A. ; Jana, U. ; Köhler, F. ; Jones, P. G. ; Dix, I. ; Fricke, T. ; König, B.



Zusammenfassung

A macrocyclic neutral ionophore 8 (X = O) capable of binding weakly coordinating anions such as nitrate and bromide in DMSO solution has been designed by a stepwise, deductive approach. The optimum geometrical arrangement of the hydrogen bond donor sites in the target ionophore was determined by DFT calculations. From these data, a suitable macrocyclic molecular framework was constructed. The ...

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