Kercher, M. and König, B. and Zieg, H. and De Cola, L. (2002) Photoinduced Energy- and Electron Transfer Processes within Dynamic Self-assembled Donor-Acceptor Arrays. J. Am. Chem. Soc. 124, 11541 - 11551.
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The synthesis and the photophysical properties of a series of noncovalently assembled donor-acceptor systems, dyads, is reported. The presented approach uses an "innocent" coordination compound, a scandium(III) acetyl acetonate derivative, as core and promotor of the dyad formation. Intercomponent photoinduced energy transfer or electron transfer within the dynamic assembly, which yields to a statistical library of donor-acceptor systems, is reported. The assemblies for energy-transfer processes are constituted by an energy donor, Ru(bpy)(3)(2+)-based component (bpy = 2,2'-bipyridine), and by an energy-acceptor moiety, anthracene-based unit, both substituted with a chelating ligand, acetyl acetone, that via coordination with a scandium ion will ensure the formation of the dyad. If N,N,N'N'-tetramethyl-2,5-diaminobenzyl-substituted acetyl acetonate ligands are used in the place of 9-acyl-anthracene, intramolecular photoinduced electron transfer from the amino derivative (electron donor) to the Ru(bpy)(3)(2+)-unit was detected upon self-assembly, mediated by the scandium complex. The photophysical processes can be studied on the lifetime of the kinetically labile complexes
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König|
|Projects:||GRK 640 Sensory photoreceptors in natural and artificial systems|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||05 Mar 2009 10:54|
|Last Modified:||31 Aug 2012 09:17|