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Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands

Hechavarría Fonseca, M. and Eibler, E. and Zabel, M. and König, B. (2003) Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands. Inorg. Chim. Acta 352, 136 - 142.

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The use of nitrogen-containing ligands for asymmetric catalysis has received growing interest in the last years. In this paper we report the synthesis of three new ligands (5c, 5d and 6) and the X-ray structure analysis of 5c and of the copper(II) complex 6-Cu(II)OTf. The catalytic activity of the ligands was tested in standard asymmetric reactions, but in most of the cases only low yields and poor enantioselectivity was obtained.

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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Identification Number:
10.1016/S0020-1693(03)00131-2 DOI
Keywords:Schiff base; Tetradentate ligand; Asymmetric catalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:05 Mar 2009 10:54
Last Modified:20 Jun 2011 14:49
Item ID:6228
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