Reichenbach-Klinke, R. and Zabel, M. and König, B. (2003) Synthesis and Structure of Cyclen Hydroxylamine Ligands and their Zinc(II)Complexes. J. Chem. Soc., Dalton Trans, 141 - 145.
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Abstract
The synthesis of two new zinc(II) complexes with 1,4,7,10-tetraazacyclododecan-1-ol and 1,4,7,10-tetraazacyclododecan-1,7-diol as ligands is described. One of these complexes is characterized by X-ray structure analysis. By coordination to the metal cation the acidity of the hydroxylamine groups of the ligands is significantly increased as confirmed by potentiometric pH titrations.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolas Korber | ||||
| Projects: | GRK 640 Sensory photoreceptors in natural and artificial systems | ||||
| Identification Number: |
| ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Regina Hoheisel | ||||
| Deposited On: | 05 Mar 2009 11:54 | ||||
| Last Modified: | 27 Aug 2012 14:57 | ||||
| Item ID: | 6229 |
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