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A Synthetic Creatinine Receptor: Imprinting of a Lewis-Acidic Zinc(II)cyclen Binding Site to Shape its Molecular Recognition Selectivity

Subat, M. and Borovik, A. S. and König, B. (2004) A Synthetic Creatinine Receptor: Imprinting of a Lewis-Acidic Zinc(II)cyclen Binding Site to Shape its Molecular Recognition Selectivity. J. Am. Chem. Soc. 126, 3185 - 3190.

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Abstract

Molecularly imprinted polymers (MIPs) from polymerizable Lewis acidic zinc(II)cyclen complexes and ethylene glycol dimethyl acrylate have been prepared. For the imprinting process the template molecule creatinine is reversibly coordinated to the zinc atom. The high strength of this interaction allows analyte binding to the MIP from aqueous solution with high affinity. Its pH dependence is used ...

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Item Type:Article
Date:2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1021/ja038980lDOI
15012148PubMed ID
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:15 Mar 2011 09:00
Item ID:6240
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