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Immobilised Zinc (II) Cyclen complexes as catalytic reagents for phosphodiester hydrolysis

Walenzyk, T. and Koenig, B. (2005) Immobilised Zinc (II) Cyclen complexes as catalytic reagents for phosphodiester hydrolysis. Inorg. Chim. Acta 358, 2269 - 2274.

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Abstract

Many hydrolases found in nature have Zn(II) ions at their active site. Artificial hydrolases as alternatives for non-enzymatic hydrolysis were prepared by attaching Zn(II) cyclen complexes with an alcohol pendant to a polymeric support. These modified polymers showed a 104-fold enhanced intrinsic reactivity for the hydrolysis of activated phosphodiesters over the non-catalysed reaction in ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1016/j.ica.2005.01.022DOI
Keywords:Phosphoester hydrolysis; Immobilised metal complexes; Zinc (II) cyclen
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:10 Mar 2011 11:31
Item ID:6248
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