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Chiral NADH Model Systems functionalized with Zn(II)-cyclen as Flavin Binding Site

Ritter, S. and Eiblmeier, M. and Michlova, V. and König, B. (2005) Chiral NADH Model Systems functionalized with Zn(II)-cyclen as Flavin Binding Site. Tetrahedron 61, 5241 - 5251.

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Abstract

A series of chiral peptides has been prepared, bearing a 1,4-dihydronicotine amide and a zinc cyclen moiety. The metal complex reversibly binds flavins in aqueous solution, while the dihydronicotine amide serves as a NADH model transferring a hydride to the flavin within the assembly. The reaction rate of the redox reaction was monitored and determined by UV spectroscopy. The reaction rates of ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1016/j.tet.2005.03.081DOI
Keywords:Flavin; NADH; Redox reaction; Zinc cyclen complex
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:10 Mar 2011 08:12
Item ID:6257
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