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Synthesis and Structure of Chiral Methoxypyrrole Amino Acids (MOPAS)

Bonauer, C. and König, B. (2005) Synthesis and Structure of Chiral Methoxypyrrole Amino Acids (MOPAS). Synthesis, 2367 - 2372.

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Abstract

A methoxypyrrole amino acid (MOPAS) resembling the structure of H2N-Val-Δ-Ala-OEt in β-sheet conformation has been prepared by a chiral auxiliary approach. The X-ray structure analysis confirms the absolute configuration of the dipeptide mimic. Standard peptide coupling procedures allow coupling of the chiral MOPAS with natural amino acids or their extension by additional MOPAS units. A tight ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1055/s-2005-870023DOI
Keywords:heterocycles - amino acids - peptides - chiral auxiliaries - imines
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:09 Nov 2010 10:32
Item ID:6258
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