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Enhanced Peptide β-Sheet Affinity by Metal to Ligand Coordination

Kruppa, M. and Bonauer, C. and Michlová, V. and König, B. (2005) Enhanced Peptide β-Sheet Affinity by Metal to Ligand Coordination. J. Org. Chem. 70, 5305 - 5308.

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Abstract

A histidine-coordinating metal complex substituted with methoxypyrrole amino acids (MOPAS) as a peptide β-sheet binder shows high affinity for a H2N−His-Leu-Leu-Val-Phe-OMe pentapeptide in DMSO solution. Within the complex, a β-sheet conformation is induced into the pentapeptide by weak intra-assembly interactions with the MOPAS units. ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1021/jo0502908DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:09 Nov 2010 10:26
Item ID:6259
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