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Low Melting Sugar-Urea-Salt Mixtures as Solvents for Organic Reactions - Estimation of Polarity and Use in Catalysis

Imperato, G. and Höger, S. and Lenoir, D. and König, B. (2006) Low Melting Sugar-Urea-Salt Mixtures as Solvents for Organic Reactions - Estimation of Polarity and Use in Catalysis. Green Chem. 8, 1051 - 1055.

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Abstract

Mixtures of sugars, sugar alcohols or citric acid with urea and inorganic salts form stable melts if heated to 70 °C. The polarity of the melts was estimated using solvatochromic dyes and found to be in the range of DMF or water, depending on the sensitivity of the dye for hydrogen bonds. To explore the use of the melts as solvents in catalysis, Rh-catalyzed hydrogenations and Pd-catalyzed Suzuki ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1039/B603660KDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:31 Jan 2011 15:05
Item ID:6271
Owner Only: item control page
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