Deutsch
Li, X. and Miltschitzky, S. and Grauer, A. and Michlová, V. and König, B. (2006) Synthesis and Peptide-binding Properties of a Luminescent Pyrimidine Zinc(II) Complex. Tetrahedron 62, 12191 - 12196.
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Abstract
The synthesis and peptide-binding properties of a Zn(II)nitrilotriacetate complex substituted with pyrimidine hydrazine amides are reported. The metal complex provides millimolar binding affinity in aqueous buffer to peptides bearing N-terminal His. The pyrimidine heterocycles intermolecularly interact with the bound peptide and quench the emission of nearby Trp residues by energy transfer.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | GRK 760, Graduiertenkolleg Medizinische Chemie | ||||
| Identification Number: |
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| Keywords: | Metal complex; Peptide binding; Histidine; Luminescence; Pyrimidine | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Regina Hoheisel | ||||
| Deposited On: | 05 Mar 2009 11:54 | ||||
| Last Modified: | 09 Nov 2010 09:09 | ||||
| Item ID: | 6272 |
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