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Synthesis and Peptide-binding Properties of a Luminescent Pyrimidine Zinc(II) Complex

Li, X. and Miltschitzky, S. and Grauer, A. and Michlová, V. and König, B. (2006) Synthesis and Peptide-binding Properties of a Luminescent Pyrimidine Zinc(II) Complex. Tetrahedron 62, 12191 - 12196.

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Abstract

The synthesis and peptide-binding properties of a Zn(II)nitrilotriacetate complex substituted with pyrimidine hydrazine amides are reported. The metal complex provides millimolar binding affinity in aqueous buffer to peptides bearing N-terminal His. The pyrimidine heterocycles intermolecularly interact with the bound peptide and quench the emission of nearby Trp residues by energy ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1016/j.tet.2006.10.019 DOI
Keywords:Metal complex; Peptide binding; Histidine; Luminescence; Pyrimidine
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:54
Last Modified:09 Nov 2010 08:09
Item ID:6272
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