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Tetrahydrofuran Cα-Tetrasubstituted Amino Acids: Two Consecutive β Turns in a Crystalline Linear Tripeptide

Maity, P. and Zabel, M. and König, B. (2007) Tetrahydrofuran Cα-Tetrasubstituted Amino Acids: Two Consecutive β Turns in a Crystalline Linear Tripeptide. J. Org. Chem. 72, 8046 – 8053.

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Abstract

The synthesis of tetrahydrofuran Cα-tetrasubstituted amino acids (TAAs) and their effect on the conformation in small peptides are reported. The synthesis starts from the protein amino acid methionine, which is protected at the C and N terminus and converted into the corresponding sulfonium salt by alkylation. Simple base treatment in the presence of an aryl aldehyde leads to the formation of ...

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Item Type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1021/jo701423wDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:55
Last Modified:08 Nov 2010 14:57
Item ID:6281
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