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2´-Oxoethyl Flavin Revisited

Svoboda, J. and König, B. and Sadeghian, K. and Schütz, M. (2008) 2´-Oxoethyl Flavin Revisited. Z. Naturforsch. 63b, 47 - 54.

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Abstract

The present work investigates the possibility of using 2'-oxoethyl flavin (2) as a starting material for the construction of more complicated flavin-based molecules. 2-Oxoethyl flavin (2), prepared by oxidative degradation of commercially available riboflavin 1, is however a rather untypical aldehyde. It prefers the hydrated gem-diol form 4 in aqueous solution. Ab initio electronic structure ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
Identification Number:
ValueType
http://www.znaturforsch.com/ab/v63b/c63b.htmUNSPECIFIED
Keywords:Flavin, Aldehyde, Hydration, Nucleophilic Attack, Reductive Amination, Local MP2
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:55
Last Modified:27 Aug 2012 13:04
Item ID:6282
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