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Thiourea-Enhanced Flavin Photooxidation of Benzyl Alcohol

Svoboda, J. and Schmaderer, H. and König, B. (2008) Thiourea-Enhanced Flavin Photooxidation of Benzyl Alcohol. Chem. Eur. J. 14, pp. 1854-1865.

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Abstract

Upon irradiation, flavin oxidises 4-methoxybenzyl alcohol to the corresponding aldehyde using aerial O(2) as the terminal oxidant. We have observed that this reaction is significantly accelerated by the presence of thiourea. A series of thiourea-functionalised flavins has been prepared from flavin isothiocyanates and their photocatalytic efficiencies have been monitored by NMR. The alcohol ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
Identification Number:
ValueType
10.1002/chem.200701319/fullDOI
18058784PubMed ID
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:55
Last Modified:27 Aug 2012 13:06
Item ID:6283
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