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Utilizing Reversible Copper(II) Peptide Coordination in a Sequence Selective Luminescent Receptor

Stadlbauer, S. and Riechers, A. and Späth, A. and König, B. (2008) Utilizing Reversible Copper(II) Peptide Coordination in a Sequence Selective Luminescent Receptor. Chem. Eur. J. 14, 2536 - 2541.

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Abstract

Although vast information about the coordination ability of amino acids and peptides to metal ions is available, little use of this has been made in the rational design of selective peptide receptors. We have combined a copper(II) nitrilotriacetato (NTA) complex with an ammonium-ion-sensitive and luminescent benzocrown ether. This compound revealed micromolar affinities and selectivities for ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
ValueType
10.1002/chem.200701442DOI
18213557PubMed ID
Keywords:chelates · crown compounds · fluorescence spectroscopy · molecular recognition · peptides
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:55
Last Modified:08 Nov 2010 13:32
Item ID:6285
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