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Copper-mediated 3-N-Arylation of Flavin

Attenberger, B. and Schmaderer, H. and König, B. (2008) Copper-mediated 3-N-Arylation of Flavin. Synthesis 11, 1767 - 1774.

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Abstract

A generally applicable method for the direct 3-N-arylation of flavins using arylboronic acids and copper acetate was developed. The reaction conditions were optimized considering the lability of flavins in basic conditions and thermal heating. Donor- and acceptor-substituted arylboronic acids were used yielding 3-N-arylflavins in moderate to good yields by C(aryl)-N(imide) bond formation. UV and ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
Identification Number:
ValueType
10.1055/s-2008-1067045DOI
Keywords:flavin, N-arylation, boronic acid, isoalloxazin, microwave, copper catalysis
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:05 Mar 2009 10:55
Last Modified:27 Aug 2012 13:05
Item ID:6290
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