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Synthesis of rigidified flavin–guanidinium ion conjugates and investigation of their photocatalytic properties

Schmaderer, Harald and Bhuyan, Mouchumi and König, Burkhard (2009) Synthesis of rigidified flavin–guanidinium ion conjugates and investigation of their photocatalytic properties. Beilstein Journal of Organic Chemistry 5 (26), online.

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Abstract

Flavin chromophores can mediate redox reactions upon irradiation by blue light. In an attempt to increase their catalytic efficacy, flavin derivatives bearing a guanidinium ion as oxoanion binding site were prepared. Chromophore and substrate binding site are linked by a rigid Kemp’s acid structure. The molecular structure of the new flavins was confirmed by an X-ray structure analysis and their ...

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Item Type:Article
Date:2009
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.3762/bjoc.5.26DOI
Keywords:flavin; guanidine; Kemp’s acid; photocatalysis; template
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:23 Jun 2009 15:10
Last Modified:24 Oct 2012 10:31
Item ID:8124
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