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Synthesis and structural investigations of alpha-peptides containing beta-aminocyclopropane dicarboxylic acids

URN to cite this document: urn:nbn:de:bvb:355-opus-1141

Zorn, Chiara (2002) Synthesis and structural investigations of alpha-peptides containing beta-aminocyclopropane dicarboxylic acids. PhD, Universität Regensburg

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Abstract (German)

Ziel der vorliegenden Arbeit war die Synthese von beta-Aminocyclopropandicarbonsäuren (b-ACC, entweder RRR (R) oder SSS (S) konfiguriert) enthaltenden alpha-Peptiden mittels einer Boc/Bn-Schutzgruppen-Strategie und deren Strukturuntersuchung durch IR, CD und NMR Spektroskopie. Das Ausmaß und die Lage der Wasserstoffbrücken in b-ACC-Derivaten wurde mittels IR- Spektroskopie und Molecular ...

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Translation of the abstract (English)

In this work the synthesis (by Boc/Bn protection strategy) of alpha-peptides containing beta-aminocyclopropane dicarboxylic acids (b-ACC, both enantiomers: RRR (R) and SSS (S)) has been developed and their conformation has been investigated by IR, CD and NMR spectroscopy. By means of IR spectroscopy and molecular dynamics calculations, the extent and location of the hydrogen-bonds in b-ACC ...

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Item Type:Thesis of the University of Regensburg (PhD)
Date:24 October 2002
Referee:Oliver (Prof. Dr.) Reiser
Date of exam:18 October 2001
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Keywords:Aminosäuren <beta-> , Zirkulardichroismus , Konformationsanalyse , Schleifen , Peptidsynthese , , beta-amino acids , turns , circular dichroism , conformational analysis , peptide synthesis
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:21 Oct 2009 13:44
Last Modified:13 Mar 2014 11:10
Item ID:9957
Owner Only: item control page

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