Absorption and Fluorescence Excitation Spectra of 9-(N-carbazolyl)-anthracene: Effects of Intramolecular Vibrational Redistribution and Diabatic Transitions Involving Electron Transfer

Evers, F. ; Giraud-Girard, J. ; Grimme, S. ; Manz, J. ; Monte, C. ; Oppel, M.

; Rettig, W. ; Saalfrank, P.

; Zimmermann, P.

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The absorption and fluorescence excitation spectra of 9-(N-carbazolyl)-anthracene (C9A) in vibronically excited S-1 states are measured and calculated by means of a simple model. Accordingly, C9A is excited from torsional states \0(j)] of the electronic ground-state So to diabatic torsional states \1l] of the bright electronically excited state S-1, which are coupled to states \2l] of the dark ...