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Synthesis, conformational investigations and applications of alpha-peptides containing cis-beta-aminocyclopropane dicarboxylic acids

URN to cite this document:
urn:nbn:de:bvb:355-opus-6446
De Pol, Silvia
Date of publication of this fulltext: 10 Apr 2007 08:10


Abstract (English)

In this work different alpha-peptides containing two enantiomers of cis-β-amino cyclopropane carboxylic acid (β-ACC) were synthesized in order to extend our knowledge regarding their conformational preferences. Alternated peptides alpha-L-Xaa-β-ACC were synthesized and their conformations were investigated by IR, CD and NMR spectroscopy. Short alpha-L-Ala-β-ACC alternated ...

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Translation of the abstract (German)

Im Rahmen der vorliegenden Arbeit wurden die beiden Enantiomere der cis-β-Amino cyclopropancarbonsäure (β-ACC) in verschiedene Peptide eingebaut und deren Konformation mit Hilfe von IR, CD und NMR Spektroskopie untersucht. Alternierende alpha-Aminosäuren-β-ACC zeigen eine helicale Konformation. Die alternierenden Hepta- und Nonapeptide aus L-Alanin und einem Enantiomer von ...

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