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The First PH-Functionalized Polyphosphazene: A Liquid Macromolecule with Highly Flexible Backbone

Raab, M., Schick, G., Fondermann, M. D., Henze, W., Weymand, U., Gschwind, R. M., Fischer, K., Schmidt, M. and Niecke, E. (2006) The First PH-Functionalized Polyphosphazene: A Liquid Macromolecule with Highly Flexible Backbone. Angewandte Chemie International Edition 45 (19), pp. 3083-3086.

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Abstract

The simplest side group: The first example of a completely H-substituted polyphosphazene I is obtained by the polycondensation of (Me2N)2PNH2 in solution at low temperature. NMR investigations and light-scattering experiments substantiate the constitution of the polymer. The conformation and a reaction pathway to I are proposed on the basis of ab initio calculations.


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Item type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/anie.200504208DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:10632
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