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Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments

Gschwind, R. M. ; Rajamohanan, P. R. ; John, M. ; Boche, G.



Abstract

An equilibrium between a monomeric solvent-separated ion pair (SSIP) and a contact ion pair (CIP) is observed directly for a representative lithium diorganocuprate, Me2CuLi·LiCN, in THF, using the 1H,6Li HOESY technique. Interestingly, crystal structures of related systems are also of the SSIP and the CIP type, whereby the latter shows a dimer as the fundamental structural element and the ...

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