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Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments

Gschwind, R. M., Rajamohanan, P. R., John, M. and Boche, G. (2000) Direct Insight into the Ion Pair Equilibria of Lithium Organocuprates by 1H,6Li HOESY Experiments. Organometallics 19 (15), pp. 2868-2873.

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Abstract

An equilibrium between a monomeric solvent-separated ion pair (SSIP) and a contact ion pair (CIP) is observed directly for a representative lithium diorganocuprate, Me2CuLi·LiCN, in THF, using the 1H,6Li HOESY technique. Interestingly, crystal structures of related systems are also of the SSIP and the CIP type, whereby the latter shows a dimer as the fundamental structural element and the ...

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Item type:Article
Date:2000
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1021/om000068nDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Item ID:10652
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