Intramolecular carbonyl…carbonyl interactions in W, Mo and Fe complexes containing the η¹-N-maleimidato ligand. X-ray, DFT and AIM studies

URN to cite this document:: urn:nbn:de:bvb:355-epub-116999
DOI to cite this document:: 10.5283/epub.11699

Palusiak, Marcin ; Rudolf, Bognia ; Zakrzewski, Janusz ; Pfitzner, Arno

; Zabel, Manfred ; Grabowski, Slawomir J.

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Date of publication of this fulltext: 23 Dec 2009 11:24

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Abstract

The crystal structures of (eta(5)-C5H5)W(CO)(3)(eta(1)-N-maleimidato) and (eta(5)-C5H5)Fe(CO)(2)(eta(1)-N-maleimidato) complexes were determined by single crystal X-ray diffraction. The molecular geometries of both structures are compared with those of the Mo analog of the W complex and ethyl-N-maleimide in order to find a relation between the geometrical features and the rate constants of the ...