Photoluminescence of Tetrameric copper(I) Iodide Complexes in Solution

URN to cite this document:: urn:nbn:de:bvb:355-epub-132786
DOI to cite this document:: 10.5283/epub.13278

Vogler, Arnd ; Kunkely, Horst

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Date of publication of this fulltext: 11 Mar 2010 05:57

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Abstract

Abstract: The colorless complexes [Cu(py)I], and [Cu(mor)I], (py = pyridine; mor = morpholine) were shown to be photoluminescent in noncoordinating solvents such as benzene, CH2Cl2, or acetone at room temperature. The red emission ( λmax= 698 nm) of the pyridine complex in benzene is quite intense (φ= 0.04) and decays with a lifetime of τ = 0.9 X s. The red photoluminescence (λmax= 654 nm) of ...