Spectroscopic Studies of Zinc Benzenethiolate Complexes: Electron Transfer to Methyl Viologen

URN to cite this document:: urn:nbn:de:bvb:355-epub-133667
DOI to cite this document:: 10.5283/epub.13366

Türk, T. ; Resch, U. ; Fox, M. A. ; Vogler, Arnd

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Date of publication of this fulltext: 16 Mar 2010 05:53

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Abstract

Mononuclear and tetranuclear zinc benzenethiolate complexes are studied by both spectroscopic and electrochemical methods. Zn(SPh)4 2- and Zn4(SPh)10 2- represent tetrahedral fragments of the cubic zinc sulfide lattice. The structured absorption spectra of the zinc benzenethiolate complexes are ascribed to intraligand transitions for the mononuclear complex and to a composite of both intraligand ...