Cadmium Benzenethiolate Clusters of Various Size: Molecular Models for Metal Chalcogenide Semiconductors

URN to cite this document:: urn:nbn:de:bvb:355-epub-133672
DOI to cite this document:: 10.5283/epub.13367

Türk, T. ; Resch, U. ; Fox, M. A. ; Vogler, Arnd

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Date of publication of this fulltext: 16 Mar 2010 05:53

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Abstract

The optical and electrochemical properties of three cadmium benzenethiolate clusters, Cd(SPh)4 2-, Cd4(SPh)10 2-, and Cd10 $4(SPh)16 4-, are studied as function of the cluster size. The Cdn clusters (n = 1,4, 10) which may represent molecular models for the semiconductor CdS show structured absorption spectra that are assigned to both ligand-to-metal charge-transfer (LMCT) and intraligand ...