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Synthesis and exploration of chiral aza-bis(oxazolines) and organocatalysts in asymmetric reactions

URN to cite this document:
urn:nbn:de:bvb:355-epub-133887
Rasappan, Ramesh
Date of publication of this fulltext: 17 May 2010 08:03


Abstract (English)

Aza-bis(oxazolines) (azabox) were introduced by our group in 20001 as structural hybrids of bis(oxazolines) and aza-semicorrins. The attractive features of these ligands are their facile attachment to organic and inorganic supports through alkylation of the central nitrogen, thus, arriving at recyclable catalysts, and the higher electron density than the corresponding bis-(oxazolines), which has ...

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Translation of the abstract (German)

Aza(bisoxazoline) (azabox) wurden von unserer Gruppe im Jahr 2000 eingeführt. Sie stellen strukturelle Hybride zwischen Bis(oxazolinen) und Aza-semicorrinen dar. Die interessante Fähigkeit dieser Liganden besteht darin, daß sie durch Alkylierung am zentralen Stickstoff einfach an organische wie auch anorganische Träger fixiert werden können, was sie recycelbar macht. Desweiteren weisen ...

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