Photochemistry of Transition Metal Complexes Induced by Outer-Sphere Charge Transfer Excitation

URN to cite this document:: urn:nbn:de:bvb:355-epub-135057
DOI to cite this document:: 10.5283/epub.13505

Vogler, Arnd ; Kunkely, Horst

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Date of publication of this fulltext: 17 Mar 2010 06:24

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Abstract

The intermolecular (outer sphere, OS) interaction of a reducing and an oxidizing metal complex generates a new optical transition involving charge transfer (CT) from the electron donor to the acceptor. OS CT transitions are classified according to the redox site (metal or ligand). Generally, the interaction between donor and acceptor is facilitated by ion pairs consisting of an oxidizing complex ...