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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-135155
- DOI to cite this document:
- 10.5283/epub.13515
Alternative links to fulltext:DOI
Abstract
The kinetically labile chloromercurates(II) have rather high stepwise formation constants in acetonitrile; even for HgCI42- a value of 1.07 X lo4 M-I was determined. The ultraviolet spectra of these complexes are characterized by ligand-to-metal charge-transfer transitions of different energies and intensities. Their photolysis leads to the formation of Hg(I) and Cl in the primary photochemical ...

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