Go to content
UR Home

Photoredox Chemistry of Chloromercurate(II) Complexes in Acetonitrile

URN to cite this document:
urn:nbn:de:bvb:355-epub-135155
DOI to cite this document:
10.5283/epub.13515
Horváth, O. ; Vogler, Arnd
[img]
Preview
PDF
(542kB)
Date of publication of this fulltext: 17 Mar 2010 06:25


Abstract

The kinetically labile chloromercurates(II) have rather high stepwise formation constants in acetonitrile; even for HgCI42- a value of 1.07 X lo4 M-I was determined. The ultraviolet spectra of these complexes are characterized by ligand-to-metal charge-transfer transitions of different energies and intensities. Their photolysis leads to the formation of Hg(I) and Cl in the primary photochemical ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons