| PDF (653kB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-135674
- DOI to cite this document:
- 10.5283/epub.13567
Alternative links to fulltext:DOI
Abstract
The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...

Owner only: item control page