Horváth, O. and Vogler, Arnd (1994) Photoredox chemistry of iodomercurate(II) complexes in acetonitrile. Inorganica Chimica Acta 221 (1-2), pp. 79-84.
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Abstract
The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1994 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Keywords: | Photochemistry; Redox reactions; Mercury complexes; Iodo complexes | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 13567 |
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