Go to content
UR Home

Photoredox chemistry of iodomercurate(II) complexes in acetonitrile

URN to cite this document:
urn:nbn:de:bvb:355-epub-135674
DOI to cite this document:
10.5283/epub.13567
Horváth, O. ; Vogler, Arnd
[img]
Preview
PDF
(653kB)
Date of publication of this fulltext: 17 Mar 2010 09:11


Abstract

The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons