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Photoredox chemistry of iodomercurate(II) complexes in acetonitrile

URN to cite this document:
urn:nbn:de:bvb:355-epub-135674
Horváth, O. ; Vogler, Arnd
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Date of publication of this fulltext: 17 Mar 2010 09:11


Abstract

The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...

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