Horváth, O. und Vogler, Arnd
Photoredox chemistry of iodomercurate(II) complexes in acetonitrile.
Inorganica Chimica Acta 221 (1-2), S. 79-84.
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The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...
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