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Synthesis, Structure and Isomerism of the [Fe3Pt(μ4-Q)(CO)9(dppm)] Clusters (Q = Se, Te; dppm = Ph2PCH2PPh2)

Pushkarevsky, Nikolay A. ; Konchenko, Sergey N. ; Scheer, Manfred


The reaction of K2[Fe3(μ3-Q)(CO)9] (Q = Se (K2[1a]), Te (K2[1b])) with [(dppm)PtCl2] leads to the addition of a [(dppm)Pt]2+ unit to a Fe2Q face of the initial cluster. By this way new heteronuclear clusters [Fe3Pt(μ3-Q)(CO)9(dppm)] were obtained possessing a butterfly-shaped cluster core bridged by a μ4-Q unit. It has been found that the resulting Fe-Pt clusters exist as equilibrium mixtures of ...


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