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Tunable radiationless energy transfer in Eu[Au(CN)₂]₃ 3H₂O by high pressure

Yersin, Hartmut, Trümbach, D., Strasser, J., Patterson, H. H. and Assefa, Z. (1998) Tunable radiationless energy transfer in Eu[Au(CN)₂]₃ 3H₂O by high pressure. Inorganic Chemistry 37, pp. 3209-3216.

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The title compound consists of two-dimensional layers of [Au(CN)₂]- complexes alternating with layers of Eu³⁺ ions. Due to this structure type, the lowest electronic transitions of the dicyanoaurates(I) exhibit an extreme red shift of Δν(max)/Δp = -130 ± 10 cm⁻¹/kbar under high-pressure application at least up to ca. 60 kbar (T = 20 K), while the shifts of the different Eu³⁺ transitions lie ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:17541
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