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Characterization of triplet sublevels by highly resolved vibrational satellite structures. Application to Pt(2-thpy)₂

Wiedenhofer, H. ; Schützenmeier, S. ; Yersin, Hartmut ; v. Zelewsky, A.


The cyclometalated Pt(2-thpy)₂ complex with thpy⁻ as the deprotonated form of 2-(2-thienyl)pyridine shows highly resolved phosphorescence and triplet excitation spectra at low temperatures when the complex is isolated in Shpol’skii matrices, as is shown for the first time. Sharp-line Shpol’skii spectra were obtained by dissolving Pt(2-thpy)₂ in n-hexane, n-heptane, n-octane, n-nonane, and ...


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