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Time-resolved vibrational structures of the triplet sublevel emission of Pd(2-thpy)₂

Schmidt, J. ; Wiedenhofer, H. ; v. Zelewsky, A. ; Yersin, Hartmut


Time-resolved phosphorescence spectra from the lowest electronic triplet of Pd(2-thpy)₂ (with 2-thpy⁻ = ortho-C-deprotonated form of 2-(2-thienyl)pyridine) (see the inset of Figure 2) are presented. The complex was isolated in a Shpol'skii matrix to obtain high resolution. The emitting triplet lies at 18418 ± 1 cm⁻¹ (electronic origin). Its zero-field splitting is less than 1 cm⁻¹ and could not ...


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