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Molecular mechanical and quantum chemical study on the species involved in the hydrolysis of cis-diamminedichloroplatinum(II) and substituted bis(ethylenediamine)dichloroplatinum(II) complexes. Part I. Reactants and products

Nikolov, G. S. ; Trendafilova, N. ; Schönenberger, Helmut ; Gust, Ronald ; Kritzenberger, J. ; Yersin, Hartmut


Cisplatin and its substituted ethylenediamine derivs., cis-PtCl2(R2en) (en = ethylenediamine, R = H, Ph, 2-, 3- and 4-PhOH) have been studied with respect to the first step of their hydrolysis reaction. The geometry of the reactants and products was detd. by mol. mechanics (MM). The MM optimized structures were used to calc. by the extended Hueckel method the charge distribution and relative ...


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