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On the lowest excited states of [Ru(bpy)₃](PF₆)₂ single crystals

Yersin, Hartmut ; Gallhuber, E.



Abstract

Polarized emission spectra of single-crystal [Ru(bpy)₃](PF₆)₂ are reported for the temperature range from 1.6 to 300 K. A detailed energy-level diagram for the emitting states including hitherto unresolved states is presented. The assignment of the excited states is accomplished within the D₃' symmetry group. The very lowest excited states being only 5-10 cm⁻¹ apart are both of E' character, ...

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