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Blue- and green-light-induced reductions and C-C bond formations with TiO2 and PbBiO2X

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Füldner, Stefan
Date of publication of this fulltext: 11 Jan 2012 07:43

Abstract (English)

The first part of this dissertation (chapter 1) deals with the green-light-induced reduction of nitrobenzenes by using dye-sensitized TiO2 and transition metal nanoparticles (chapter 1.2) or nanomolar amounts of urea derivatives (chapter 1.3). In the case of transition metal nanoparticles, clusters were found by TEM and dihydrogen gas was detected by GC-MS. The dependence of the conversion on ...


Translation of the abstract (German)

Der erste Teil dieser Dissertation (Kapitel 1) behandelt selektive photokatalysierte Reduktionen von Nitrobenzolderivaten zu ihren entsprechenden Anilinen. Farbstoffsensibilisertes TiO2 (Degussa P25) bildet den eigentlichen Photokatalysator, der unter Bestrahlung von grünem Licht (LEDs 530 nm ± 10 nm) oder Sonnenlicht und Additiven Nitrobenzolderivate zu ihren Anilinen reduziert. Zum einen sind ...


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