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The triplet state of organo-transition metal compounds. Triplet harvesting and singlet harvesting for efficient OLEDs

Yersin, Hartmut ; Rausch, A. F. ; Czerwieniec, R. ; Hofbeck, T. ; Fischer, T.


Based on a very comprehensive set of experimental data and on theoretical models, an understanding of the triplet state properties of organo-transition metal compounds is worked out. Important trends and guidelines for controlling photophysical properties are revealed. In this respect, we focus on spin–orbit coupling (SOC) and its importance for radiative as well as for nonradiative transitions ...


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