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Complexity in "Simple" Electrolyte Solutions: Ion Pairing in MgSO4(aq)

Buchner, Richard ; Chen, T. ; Hefter, Glenn


A detailed investigation of aq. solns. of MgSO4 has been made by dielec. relaxation spectroscopy over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) and concns. (0.017 ≤ c/M ≤ 2.24). Detailed anal. of the spectra shows conclusively, as has long been inferred from ultrasonic absorption studies, the simultaneous presence of double solvent sepd. (2SIP), solvent-shared (SIP), and contact (CIP) ion ...


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