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Temperature dependence of the dielectric properties and dynamics of ionic liquids

Hunger, J. ; Stoppa, A. ; Schrödle, S. ; Hefter, Glenn ; Buchner, Richard


Dielec. spectra were measured for eight, mostly imidazolium-based, room temp. ionic liqs. (RTILs) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) and temps. (5 ≤ θ/°C ≤ 65). Detailed anal. of the spectra shows that the dominant low frequency process centered at ca. 0.06 to 10 GHz (depending on the salt and the temp.) is better described using a sym. broadened Cole-Cole model rather than the ...


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