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Dielectric Relaxation Study of the Ion Solvation and Association of NaCF3SO3, Mg(CF3SO3)2, and Ba(ClO4)2 in N,N-Dimethylformamide

Placzek, A. ; Hefter, Glenn ; Rahman, H. M. A. ; Buchner, Richard


Solns. of sodium trifluoromethanesulfonate, magnesium trifluoromethanesulfonate, and barium perchlorate in N,N-dimethylformamide (DMF) were investigated using broadband dielec. relaxation spectroscopy at 25 °C. All spectra were dominated by a solvent relaxation process centered at ∼15 GHz but also exhibited one (for NaCF3SO3) or two (for the 2:1 salts) low-amplitude processes, centered at ...


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