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Features of ion hydration and association in aqueous rubidium fluoride solutions at ambient conditions

Fedotova, M. V. ; Kruchinin, S.E. ; Rahman, H.M.A. ; Buchner, Richard



Abstract

Aq. RbF solns. have been investigated at ambient conditions by dielec. relaxation spectroscopy (DRS) over the concn. range of 0 ≤ c/M ≤ 5 and by statistical mechanics (RISM integral equation theory) in the concn. range of 2.15-9.18 M. The behavior of the dielec. spectra and their characteristic parameters (dispersion amplitudes and relaxation times) is discussed, as well as the pair correlation ...

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