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On the collective network of ionic liquid/water mixtures. II. Decomposition and interpretation of dielectric spectra

Schröder, C. ; Hunger, J. ; Stoppa, A. ; Buchner, Richard ; Steinhauser, O.


This study deals with the dielec. spectra of mixts. of the ionic liq. 1-butyl-3-methyl-imidazolium (BMIM+) tetrafluoroborate with water at three selected mole fractions 0.767 ≤ xH2O ≤ 0.967. The focus lies on the comparison of exptl. and computational data. On the one hand, a computational anal. permits a complete decompn. of spectra, both with respect to dynamical behavior (translation and ...


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