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Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid

Sangoro, Joshua ; Iacob, Ciprian ; Serghei, A. ; Naumov, S. ; Galvosas, P. ; Kärger, J. ; Buchner, Richard ; Wespe, C. ; Bordusa, F. ; Stoppa, A. ; Hunger, J. ; Kremer, Friedrich



Abstract

Broadband dielec. and terahertz spectroscopy (10-2-10+12 Hz) are combined with pulsed field gradient NMR (PFG-NMR) to explore charge transport and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liq. The dielec. spectra are interpreted as superposition of high-frequency relaxation processes assocd. with dipolar librations and a cond. contribution. The latter ...

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