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Ion association and solvation of perchlorate salts in N,N-dimethylformamide and N,N-dimethylacetamide

Wurm, B. ; Münsterer, M. ; Richardi, J. ; Buchner, Richard ; Barthel, Josef


The results of dielec. relaxation expts. on solns. of LiClO4, NaClO4 and Bu4NClO4 in N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMA), performed at 25 °C in the frequency range 0.2 ≤ ν/GHz ≤ 89 are presented. For all electrolytes, a solute relaxation process due to ion pairs is obsd. in addn. to the solvent relaxation. The alkali salts form predominantly solvent-shared ion pairs in ...


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